Nucleophilic attack Samenvattingen, Aantekeningen en Examens

Classifications of proteins are based on.... correct answer: - position in the cell (membrane/soluble/extracellular) - function (transporter/enzyme/structural/hormone) - other molecules associated w/ it (glycoprotein - sugar, lipoprotein - lipid) A salt bridge is an....bond and is an example of a.....interaction correct answer: ionic, non-covalent Are salt bridges easier to break in biochem? Why? correct answer: - Yes- Interacting w/ surrounding solvent (water) Is an O bonded to a ...

agarose and agar correct answer: polysaccharides used to run DNA gels and for microbial plates bacterial cell walls correct answer: contain polysaccharides in their peptidoglycan layer lectins correct answer: are proteins that bind to sugars protein glycolsylation correct answer: assists in folding and cellular recognition, e.g. ABO blood groups -ose correct answer: indicates a molecule is some kind of carb blood group antigens correct answer: glycoproteins containing differ...

AQA A-Level CHEMISTRY 7405/2 Paper 2 Organic and Physical Chemistry Mark scheme June 2022. Brown colour removed Goes colourless Allow (orange) brown to colourless Allow purple to colourless 1 (AO3) Question Answers Additional Comments/Guidelines Mark 01.5 As T increases rate (1/t ) increases OR time for completion decreases Exponentially OR By a greater/ increasing factor Many more particles have E ≥ Ea Or rate increases more and more as temp increases i.e. description of exponen...

1. Reaction of ethyl magnesium bromide with water will generate? a. ethanol b. ethane c. butane d. ethyl magnesium hydroxide e. a peroxide - b 2. Under conditions of thermodynamic control, product distribution is governed by: a. the relative stabilities of the products b. the relative energies of the transition states leading to the products c. the rate at which each product is formed d. a and b e. b and c - a 3. Which of the following statements is false for the reduction of camphor...

13.3 Elimination Reactions in HalogenoalkanesHow do halogenoalkanes typically react? By nucleophilic substitution How do halogenoalkanes react under different conditions? By elimination How does elimination reactions occur? A hydrogen halide is eliminated from the molecule, leaving a double bond in its place so that an alkene is formed What is the OH- ion from aqueous sodium or potassium hydroxide? A nucleophile and its lone pair will attack a halogenoalkane at C

SN1 Reaction - ANSWER- Unimolecular nucleophilic substitution - 2 steps - Starting with enantiomerically pure product tends to result in some degree of racemization - Retention AND inversion at stereocenter (R and S) - 1 nucleophile is replaced by another nucleophile - Carbocation INTERMEDIATE forms - Rate is dependent only on substrate concentration 1. LG leaves, forming a carbocation 2. Nucleophile attacks the carbocation, forming the product SN2 Reaction - ANSWER- Bimolecular nuc...

TAMU CHEM 238 FINAL EXAM QUESTIONS AND ANSWERS RATED A+ 1. Reaction of ethyl magnesium bromide with water will generate? a. ethanol b. ethane c. butane d. ethyl magnesium hydroxide e. a peroxide b 2. Under conditions of thermodynamic control, product distribution is governed by: a. the relative stabilities of the products b. the relative energies of the transition states leading to the products c. the rate at which each product is formed d. a and b e. b and c a 3. Which of the followi...

Cumulated Diene correct answers double bonds are adjacent Conjugated Diene correct answers double bonds separated by 1 single bond Isolated Diene correct answers double bonds separated by more than 1 single bond Heteroatoms correct answers may be involved in conjugated dienes atom that isn't a carbon atom Diene Formation correct answers elimination using a strong, bulky base t-BuOK Single Bonds in Conjugated Diene correct answers shorter than typical will freely rotate allows...

How is malonyl-CoA formed? correct answer: Carboxylation of acetyl-CoA to form malonyl-CoA requires two steps (both use acetyl-CoA carboxylase). 1. The enzyme, complexed with biotin, acquires CO2 from HCO3 - a. Requires 1 ATP 2. The carbon is transferred to acetyl-CoA to form malonyl-CoA The overall reaction is irreversible and commits the molecule to fatty acid synthesis. Phosphate is added to HCO3 - and then removed so that biotin-carboxylase can grab the carbon. The carbon is donated to...

UMICH CHEM 210 - Exam #3 - Reaction Mechanisms 100% Correct SN1 Reaction - ANSWER- Unimolecular nucleophilic substitution - 2 steps - Starting with enantiomerically pure product tends to result in some degree of racemization - Retention AND inversion at stereocenter (R and S) - 1 nucleophile is replaced by another nucleophile - Carbocation INTERMEDIATE forms - Rate is dependent only on substrate concentration 1. LG leaves, forming a carbocation 2. Nucleophile attacks the carbocati...